09/23/21 News Interesting scientific research on 1111-67-7

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Reference of 1111-67-7, You could be based in a university, combining chemical research with teaching; or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries. In an article, authors is Tzeng, Biing-Chiau, once mentioned the application of Reference of 1111-67-7, Name is Cuprous thiocyanate,molecular formula is CCuNS, is a conventional compound.

The reaction of a C3-symmetric tridentate ligand, N,N?,N?-(4,4?,4?-nitrilotris(4,1-phenylene)) triisonicotinamide (L), with various d10-metal salts of CuI, Cu(SCN), and M(ClO4)2 (M = Zn, Cd) led to four metal-organic materials of {[(Cu2I2)(L)2] ·4DMF·2MeOH}n (1), {[Cu(L)2(NCS) 2]·3DMF}n (2), and {[M(L)2(ClO 4)2]·4EtOH}n (M = Zn 3 and Cd 4), respectively, which have been isolated and structurally characterized by X-ray diffraction studies. The X-ray analysis revealed that the interlocking of the 1-D double-zigzag chains of 1-4 into the macrocycles of the adjacent chains generates a novel 2-D (1-D ? 2-D) polyrotaxane framework. In these 2-D polyrotaxane frameworks, the C3-symmetric tridentate ligand, L, only adopts a mu2-bridging mode, and the third arm is free. In addition, 1-4 are all emissive with dual emissions (431-452 and 558-570 nm) in the solid state at room temperature and at 77 K, which are suggested to be due to an intraligand transition of L based on the high similarities in emission energies to that of L.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”