Synthetic Route of 1111-67-7, Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. Mentioned the application of 1111-67-7, Name is Cuprous thiocyanate.
The reaction of CuSCN (or CuCl2) in the presence of excess KSCN directed by viologen-based linear templates in a dimethyl formamide-methanol system affords six coordination polymers, {(MV)[Cu2(SCN) 4]}n (1, MV2+ = 1,1?-dimethyl-4,4?- bipyridinium), {(PrV)[Cu2(SCN)4]}n (2, PrV 2+ = 1,1?-dipropyl-4,4?-bipyridinium), {(iPV)[Cu 2(SCN)4]}n (3, iPV2+ = 1,1?-diisopropyl-4,4?-bipyridinium), [(1-iBV)Cu2(SCN) 3]n (4, 1-iBV2+ = 1-isobutyl-4,4?- bipyridinium), {(iBV)[Cu2(SCN)4]}n (5, iBV 2+ = 1,1?-diisobutyl-4,4?-bipyridinium), and {(PtV)[Cu2(SCN)4]}n (6, PtV2+ = 1,1?-dipentyl-4,4?-bipyridinium). The [Cu2(SCN) 4]n anion in compounds 1, 3 and 5 adopts an infinite two-dimensional polypseudorotaxane architecture and proved effectively that the stoppers at the end can enhance the polyrotaxane formation in the crystalline state, whereas the anion moieties in compounds 2 and 6 exhibit one-dimensional linear architectures, suggesting dethreading from envelopes once solidifying from solution phase. Compound 4 was found to be a two-dimensional coordination polymer with the organic ligand carrying a single charge. The side chain template effect of substituted group, UV-Vis diffuse reflectance spectra in the solid state and TGA properties of the six complexes are investigated.
Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 1111-67-7 is helpful to your research.
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”