One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Product Details of 1111-67-7, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS
New amido and imido bridged complexes of copper – Syntheses and structures of [{Li(OEt2)}2][Cu(NPh2)3], [ClCuN(SnMe3)3], [{CuN(SnMe3)2}4], 1?[Cu16(NH2 tBu)12Cl16], {CuNHtBu}8]
The reactions of stannylated and lithiated amines with coppersalts (halogenides, thiocyanates) lead to amido and imido bridged complexes which contain one to twelve metal atoms. [{Li(OEt2)}2][Cu(NPh2)3] (1) results from the reaction of CuCl with LiNPh2 in the presence of trimethylphosphine. With N(SnMe3)3, CuCl reacts to the donor-acceptor complex [ClCuN(SnMe3)3] (2) that is transformed into the tetrameric complex [{CuN(SnMe3)2}4] (3) by thermolysis. 3 can also be obtained by the reaction of LiN(SnMe3)2 with Cu(SCN)2. While terminally bound in 1, the amido ligand is mu2-bridging between copper atoms in compound 3. The influence of the alkyl amide’s leaving group can be seen from a comparison of the reactivity of Me3SnNHtBu and LiNHtBu, respectively. With Me3SnNHtBu, CuCl2 forms the polymeric compound 1?[Cu16(NH2 tBu)12Cl16] (4) whereas in the case of LiNHtBu with both CuCl and CuSCN, the complex [{CuNHtBu}8] (5) is obtained. The latter contains two planar Cu4N4-rings similar to those in 3. If a mesityl group is introduced at the lithium amide, different products are accessible. Both, CuBr and CuSCN, lead to the formation of [Li(dme)3][Cu6(NHMes)3(NMes)2] (6) whose anion consists of a prismatic copper core with mu2-bridging amido and mu3-bridging imido ligands. In the presence of.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Product Details of 1111-67-7, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 1111-67-7, in my other articles.
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”