Synthetic Route of 1111-67-7, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a article£¬once mentioned of 1111-67-7
Synthesis and structural characterization of seven copper(I) complexes with 3-amino-5,6-dimethyl-1,2,4-triazine and triphenylphosphine/triphenylarsine
Seven new copper(I) complexes containing 3-amino-5,6-dimethyl-1,2,4- triazine (ADMT), [Cu(mu-Cl)(ADMT)(PPh3)]2 (1), [Cu(mu-NCS)(ADMT)(PPh3)]2 (2), [Cu(ADMT)(PPh 3)2Cl] (3), [Cu(ADMT)(PPh3)2Br] (4), [Cu(mu-Cl)(ADMT)(AsPh3)]2 (5), [Cu(mu-Br)(ADMT) (AsPh3)]2 (6) and [Cu(ADMT)(AsPh3) 2I] (7) have been synthesized by the reactions of CuX (X = Cl, Br, I, SCN) with triphenylphosphine/triphenylarsine EPh3 (E = P for 1-4; E = As for 5-7) and ADMT in mixed solvents. Complexes 1-7 have been characterized by IR, NMR, luminescence, elemental analyses and X-ray diffraction. In 1, 2, 5 and 6, the intermolecular hydrogen bonds of type I R22(8) are formed by two N-H donors and two N atoms from two ADMT ligands. In 1-7, the intramolecular hydrogen bond of type II R11(6) is formed between one N-H donor from ADMT and one halide ion. In 1, 2, 5 and 6, the halide ions and thiocyanate ions bridge two copper atoms to form the parallelogram Cu2X2, which are further linked to form infinite zigzag chains along a-axis through the hydrogen bond of type I R2 2(8).
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1111-67-7
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”