Extracurricular laboratory:new discovery of Cuprous thiocyanate

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Two polyknotted topological isomers of copper(I) 3,5-bis(4-pyridyl) pyrazolates

Two unprecedented 3D polyknotted isomers, arisen from different linkage modes of SCN-, were obtained from 3,5-bis(4-pyridyl)-1H-pyrazole (Hbppz) and CuSCN under different conditions.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

More research is needed about Cuprous thiocyanate

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Synthetic Route of 1111-67-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a Article£¬once mentioned of 1111-67-7

Transport and chemistry at electroactive interfaces studied using line-imaging Raman spectroscopy

Line-imaging Raman spectroscopy provides a contiguous series of Raman spectra along a line in space. The resulting image provides a one-dimensional spatial profile containing information about the bonding and chemical environment being sampled. The instrument configuration described here has a spatial resolution of about 5 mum and a spectral resolution of approximately 10 cm-1. Two examples highlight the use of in situ line-imaging Raman spectroscopy in electrochemical engineering. In the first example, the cation transport and redox characteristics of a thin (? 36 nm) nickel hexacyanoferrate film are probed. The oxidation state of iron centers within the nickel hexacyanoferrate thin film is shown to be readily modulated between ferric and ferrous states in the freshly prepared film. However, repeated cycling results in an irreversible loss of capacity as the iron centers no longer are able to efficiently switch into the ferric state. In the second example, we demonstrate the simultaneous imaging of a thin film of semiconducting copper (I) thiocyanate and the electrolyte chemistry from which the film was deposited. We show that copper thiocyanate electrodeposits have the beta crystal form and the deposition involves a CuSCN+ precursor that forms via homogeneous solution phase chemistry upon addition of copper sulfate to a potassium thiocyanate containing electrolyte. (C) 2000 Elsevier Science B.V. Line-imaging Raman spectroscopy provides a contiguous series of Raman spectra along a line in space. The resulting image provides a one-dimensional spatial profile containing information about the bonding and chemical environment being sampled. The instrument configuration described here has a spatial resolution of about 5 mum and a spectral resolution of approximately 10 cm-1. Two examples highlight the use of in situ line-imaging Raman spectroscopy in electrochemical engineering. In the first example, the cation transport and redox characteristics of a thin (?36 nm) nickel hexacyanoferrate film are probed. The oxidation state of iron centers within the nickel hexacyanoferrate thin film is shown to be readily modulated between ferric and ferrous states in the freshly prepared film. However, repeated cycling results in an irreversible loss of capacity as the iron centers no longer are able to efficiently switch into the ferric state. In the second example, we demonstrate the simultaneous imaging of a thin film of semiconducting copper (I) thiocyanate and the electrolyte chemistry from which the film was deposited. We show that copper thiocyanate electrodeposits have the beta crystal form and the deposition involves a CuSCN+ precursor that forms via homogeneous solution phase chemistry upon addition of copper sulfate to a potassium thiocyanate containing electrolyte.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Extended knowledge of 1111-67-7

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Two new supramolecular compounds induced by novel vinylpyridine cationic templates: synthesis, structures and enhanced photocatalytic properties

Abstract: Two novel complexes {(Pepy)[Cu2(SCN)4]}n (1) and {(Pepy)[Cu2Br4]}n (2) [Pepy=1-2-(Pyridinium-1-yl)-1-ethenyl) pyridinium] based on vinylpyridinium organic cation and cuprous salts have been synthesized and characterized by X-ray diffractometry. Compound 1 has a 2D polypseudorotaxane structure and compound 2 presents a 1D chain structure. Furthermore, the thermal gravimetric analysis (TGA), UV?Vis diffuse reflectance spectra, the morphology and the photocatalytic performances were studied carefully. Remarkably, both 1 and 2 exhibited good photocatalytic degradation abilities towards some dyes. Graphical Abstract: Two novel complexes {(Pepy)[Cu2(SCN)4]}n and {(Pepy)[Cu2Br4]}n [Pepy=1-2-(Pyridinium-1-yl)-1-ethenyl) pyridinium] based on vinylpyridinium cation and cuprous salts have been synthesized. They exhibited diverse structures and good photocatalytic properties.[Figure not available: see fulltext.].

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Final Thoughts on Chemistry for Cuprous thiocyanate

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Enantioselective alpha-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C?CF3 and C?C bonds

A dual copper/chiral phosphoric acid-catalyzed asymmetric tandem remote C(sp3)-H/unactivated alkene functionalization reaction triggered by radical trifluoromethylation of unactivated alkenes for the concomitant construction of C?CF3 and C?C bonds was described. This approach provided an efficient method for the synthesis of valuable chiral trifluoromethylated indole derivatives with excellent regio-, chemo-, and good enantioselectivity.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Top Picks: new discover of 1111-67-7

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Chemistry is traditionally divided into organic and inorganic chemistry. name: Cuprous thiocyanate, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1111-67-7

High-efficiency perovskite solar cell using cobalt doped nickel oxide hole transport layer fabricated by NIR process

Lead halide perovskite solar cells (PVSCs) have potential toward commercialization because of their high efficiency and low cost. The hole transport layer (HTL) of p-i-n perovskite solar cell is usually made of NiOX. However, the NiOX needs to be processed at 300 C for 15 min for good hole transport property. This long heating time prohibits the development of continuous commercial process. Thus, a rapid heating process for the NiOX film deposition is critical to realize the commercialization of PVSCs in the future. In this study, we develop a facile method to obtain high quality NiOX films annealed by NIR in a short time of 50 s. A short-wave NIR lamp at 2500 K was used to systematically investigate the effect of NIR intensity on the film quality of sol-gel NiOX. The PVSCs fabricated from NIR-annealed NiOX (NIR-NiOX) film show a comparable power conversion efficiency (PCE) to those fabricated from traditional hot-plate annealed-NiOX (HP-NiOX). In addition, the NIR annealed cobalt-doped NiOX (NIR-Co:NiOX) was synthesized to replace pristine NIR-NiOX. The PCE of PVSCs fabricated from this new NiOX film can be increased from 15.99% to 17.77%, which is due to the efficient hole extraction, less charge accumulation, and reducing Voc loss resulting from the improved hole mobility, reduced interface resistance and well-matched work function. Our study paves a way to fulfill the requirements of low cost and low energy consumption of large scale production of high efficiency PVSCs.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Awesome and Easy Science Experiments about 1111-67-7

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Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper

Aromatic and heteroaromatic diazonium salts were efficiently converted into the corresponding trifluoromethylthio- or selenoethers by reaction with Me4NSCF3 or Me4NSeCF3, respectively, in the presence of catalytic amounts of copper thiocyanate. These Sandmeyer-type reactions proceed within one hour at room temperature, are applicable to a wide range of functionalized molecules, and can optionally be combined with the diazotizations into one-pot protocols.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Simple exploration of 1317-39-1

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Process for preparing aminobenzocyclobutenes

A process for preparing a 3- or 4-aminobenzocyclobutene comprises aminating a 3- or 4-halo- or sulfonyloxybenzocyclobutene reactant with an aminating agent by heating at a temperature from about 80 C. to a temperature at which dimerization or oligomerization of a benzocyclobutene reactant or product is a significant side reaction, in the presence of a metal-containing catalyst, for a time sufficient to aminate the halo- or sulfonyloxybenzocyclobutene reactant. In another aspect, this invention relates to a process for making a 3- or 4-phthalimido- or maleimidobenzocyclobutene, comprising reacting a 3- or 4-halobenzocyclobutene reactant with a phthalimide or maleimide compound in the presence of a metal-containing catalyst. The resulting phthalimido- or maleimidobenzocyclobutene can be hydrolyzed to a 3- or 4-aminobenzocyclobutene.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Can You Really Do Chemisty Experiments About 1111-67-7

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Trifluoromethylthiolation and Trifluoromethylselenolation of alpha-Diazo Esters Catalyzed by Copper

alpha-Diazo esters are smoothly converted into the corresponding trifluoromethyl thio- or selenoethers by reaction with Me4NSCF3or Me4NSeCF3, respectively, in the presence of catalytic amounts of copper thiocyanate. This straightforward method gives high yields under neutral conditions at room temperature and is applicable to a wide range of functionalized molecules, including diverse alpha-amino acid derivatives. It is well-suited for the late-stage introduction of trifluoromethylthio or -seleno groups into drug-like molecules.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Archives for Chemistry Experiments of Bis(acetylacetone)copper

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Reference of 13395-16-9, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.13395-16-9, Name is Bis(acetylacetone)copper, molecular formula is C10H16CuO4. In a Article£¬once mentioned of 13395-16-9

Phosphate-free synthesis, optical absorption and photoelectric properties of Cu2ZnGeS4 and Cu2ZnGeSe4 uniform nanocrystals

Copper-based quaternary chalcogenide semiconductor Cu2ZnGeS 4 and Cu2ZnGeSe4 nanocrystals have been synthesized successfully via a simple and convenient one-pot phosphine-free solution approach. Oleylamine was used as both the solvent and reductant for Se or S and benefited the formation of homogeneous quaternary nanocrystals. Scanning transmission electron microscopy-EDS elemental mapping confirms the uniform spatial distribution of four elements in nanocrystals. UV-Vis absorption spectra of Cu2ZnGeS4 and Cu2ZnGeSe4 nanocrystals show strong photon absorption in the entire visible range. The photoresponsive behavior indicates the potential application of Cu 2ZnGeSe4 nanocrystals in solar energy conversion systems.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

A new application about Copper(I) oxide

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Novel substituted xanthone carboxylic acid compounds

Compositions containing and methods employing, as the essential ingredient, novel substituted xanthone carboxylic acid compounds which are useful in the treatment of allergic conditions. Methods for preparing these compounds and compositions and intermediates therein are also disclosed. 6-Acetylxanthone-2-carboxylic acid is illustrated as a representative compound.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”