Chemical engineers work across a number of sectors, processes differ within each of these areas, but chemistry and chemical engineering roles are found throughout, creation and manufacturing process of chemical products and materials. Product Details of 1111-67-7, Name is Cuprous thiocyanate, Product Details of 1111-67-7, molecular formula is CCuNS. In a article,once mentioned of Product Details of 1111-67-7
Seven novel complexes (C1?C7) were synthesized by the interaction between Cu(I) metal cation, L1, L2, L3, X and PPh3, where L1?L3 are derivatives of ((pyridine-2-ylmethylene)amino)phenol imine ligands and X = Cl?, Br?, I?, NCS?. All the complexes were characterized using infrared, 1H NMR and 31P NMR spectroscopies. The crystal structures of C1?C7 were also determined using single-crystal X-ray diffraction. The organization of the crystal structures and the intermolecular interactions are discussed. The supramolecular assemblies are driven by cooperative pi?pi interactions and hydrogen bonds, followed by CH?pi linkages. The potential anticancer effect of C1?C7 was assessed for human glioblastoma cells using several anticancer experiments, which showed that these complexes have marked anticancer property against U87 cells. It was also found that the minimum and maximum anticancer effects are shown by C3- and C4-treated samples, respectively. Furthermore, theoretical approaches were used to investigate the nature of metal?ligand interactions which suggest a closed-shell and electrostatic character for Cu?N, Cu?P and Cu?X bonds.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”