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The reaction of a C3-symmetric tridentate ligand, N,N?,N?-(4,4?,4?-nitrilotris(4,1-phenylene)) triisonicotinamide (L), with various d10-metal salts of CuI, Cu(SCN), and M(ClO4)2 (M = Zn, Cd) led to four metal-organic materials of {[(Cu2I2)(L)2] ·4DMF·2MeOH}n (1), {[Cu(L)2(NCS) 2]·3DMF}n (2), and {[M(L)2(ClO 4)2]·4EtOH}n (M = Zn 3 and Cd 4), respectively, which have been isolated and structurally characterized by X-ray diffraction studies. The X-ray analysis revealed that the interlocking of the 1-D double-zigzag chains of 1-4 into the macrocycles of the adjacent chains generates a novel 2-D (1-D ? 2-D) polyrotaxane framework. In these 2-D polyrotaxane frameworks, the C3-symmetric tridentate ligand, L, only adopts a mu2-bridging mode, and the third arm is free. In addition, 1-4 are all emissive with dual emissions (431-452 and 558-570 nm) in the solid state at room temperature and at 77 K, which are suggested to be due to an intraligand transition of L based on the high similarities in emission energies to that of L.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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A method is found to significantly improve the p-type conductivity of CuSCN modified by incorporating triethylamine coordinated Cu(II) sites in its structure. It is done by mixing triethylamine hydrothiocyanate with CuSCN in propyl sulfide solution and allowing it to stand still in the dark for a few weeks in a closed sample tube. XRD and SEM analyses point to the modification of the CuSCN material. The Hall effect measurements clearly show a significant enhancement of hole concentration and hence of p-type conductivity. A maximum conductivity of 1.42 S m?1 is achieved for the structurally modified CuSCN compared to that of 0.01 S m?1 for ordinary CuSCN. AC impedance analysis of solid-state dye-sensitized solar cells based on this material clearly shows the reduction of bulk resistance of the cell with the use of modified CuSCN. This decrease in resistance has been attributed to the enhancement of conductivity and better pore filing of modified CuSCN inside the TiO2 matrix. As such, the solar cell performance gradually increases to an optimum value beyond which it decreases. The best result obtained for conversion efficiency is 3.4% at AM 1.5, which is a 41.8% enhancement from the best reported value for a dye-sensitized solid-state solar cell using CuSCN as a hole conducting material. The best efficiency value obtained is 14 times higher than that obtained for the dye-sensitized solid-state solar cell made with ordinary CuSCN.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The present invention relates to combinations of 4-bromo-2-(4-chloro-phenyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, or a salt thereof, and copper or zinc compounds which provide an improved protecting effect against fouling organisms. More particularly, the present invention relates to compositions comprising a combination of 4-bromo-2-(4-chlorophenyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, or a salt thereof, together with one or more copper or zinc compounds selected from Cu2O, Cu(OH)2, CuSO4, copper pyrithione, CuSCN, CuCO3, ZnO, ZnCl2, ZnSO4, zineb, and zinc pyrithione; in respective proportions to provide a synergistic effect against fouling organisms and the use of these compositions for protecting materials against fouling organisms. This invention thus relates to the field of protection of materials, such as underwater objects, protection of wood, wood products, biodegradable materials and coatings.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The present disclosure is related to a family of oil-based dispersions of organic and inorganic metal compounds for use as a hydrogen sulfide scavenger in asphalt, and the preparation thereof. These dispersions comprise organic and inorganic metal compounds, organic solvents, an organoclay suspension agent, an emulsifier and optionally a polymeric stabilizer. The organic and inorganic metal compounds are in the form of micron-sized particles. Copper-based dispersions are particularly effective at reducing the hydrogen sulfide emission of asphalt in the presence of polyphosphoric acid.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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5-Etherified 2-pyridinecarboxylic acids, e.g. those of the formula STR1 R = phenyl or (alkyl, alkoxy, halogeno, CF3, CN, CONH2 or NH2)-phenyl R’ = H or carboxy X = O or S, m = 1-4 or functional derivative thereof, are hypotensive agents.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. We’ll be discussing some of the latest developments in chemical about CAS: Application of 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. Application of 1111-67-7In an article, authors is Li, Jinshan, once mentioned the new application about Application of 1111-67-7.

Acid thiocyanate leaching of gold was investigated in the presence of ferric sulfate as an oxidant. According to leaching kinetic studies the initial rate of gold leaching is slow, and not significantly dependent on thiocyanate (0.05-0.2 M) and ferric (0.1-1.0 g/L) concentrations. Ferrous and cupric ions had no effect on leaching kinetics under the conditions studied. In contrast, silver (I) and copper (I) ions significantly impeded the rate of gold leaching. The electrochemical experiments (linear sweep voltammetry and chronoamperometry) indicated that the anodic reaction for gold leaching in acid thiocyanate solutions is the limiting step for the leaching process. Gold dissolution and thiocyanate oxidation participate simultaneously in the anodic process. The addition of thiourea noticeably enhanced the rate of gold leaching. Fourier transform infrared spectroscopy (FTIR) studies demonstrated that thiocyanate and its complexes with the metal ions involved in the leaching systems (Fe (III), Cu (II), Cu (I) and Ag (I)) had very weak adsorption properties at the gold surface.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Chemistry involves the study of all things chemical – chemical processes, chemical compositions and chemical manipulation – in order to better understand the way in which materials are structured, how they change and how they react in certain situations. COA of Formula: CCuNS, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. COA of Formula: CCuNSIn an article, authors is Zarca, Gabriel, once mentioned the new application about COA of Formula: CCuNS.

For the first time, a theoretical semipredictive approach based on the soft-Statistical Associating Fluid Theory equation of state is presented to model the complexation reaction between carbon monoxide (CO) in a combined ionic liquid (IL) plus a copper(I) metallic salt media in terms of the gas solubility as a function of temperature, pressure, and composition. Two different degrees of molecular approximation are tested. In the first approach, the IL-metal salt mixture is treated as a single compound whose parameters are modified according to the concentration of the metallic salt. In the second approach, both compounds are treated as independent species, enhancing the predictive capability of the model. The complexation between CO molecules and the metal salt is reproduced by adding specific cross-association interaction sites that simulate the reaction. The density of the doped IL and the CO solubility are described in quantitative agreement with the experimental data at different operating conditions.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The salts Cu(CN) and Cu(NCS) react with 2,2′-biquinoline (bq = C18H12N2) to give the adducts <n> (1) and <n> (2).Complex (1) crystallyzes in space group C2/m with cell dimensions a = 13.626(2), b = 15.322(2), c = 7.908(1) Angstroem, beta = 95.89(1) deg, and Z = 2.It consists of chains of CN-bridged copper atoms, each copper being either linearly or tetrahedrally co-ordinated.The tetrahedral copper is also co-ordinated to bq.Pairs of bq molecules belonging to paralell chains stack with an interplanar spacing of 3.35 Angstroem.Complex (2) is microcrystalline and from hot dimethyl sulphoxide gives crystals of (3).The polarization properties of the i.r. and electronic bands of complex (1) have been determined.In the optical spectrum two metal-to-ligand charge-transfer transitions could be detected.Comparison of the spectroscopic properties of the three compounds indicates a lower degree of polymerization for (3).

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Chemical shifts, DeltaE, of the K-absorption discontinuity in several compounds of copper possessing formal oxidation states between 0 and III have been measured.The shifts show a parabolic dependence on the formal oxidation state as well as on the effective atomic charge, q, on copper.Anomalous chemical shifts shown by some of the compounds are discussed in terms of the bonding in these compounds.The DeltaE values have also been correlated with the core electron binding energies obtained from X-ray photoelectron spectroscopy.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Catalytic decomposition of cyclohexyl and 1-methylcyclohexyl peroxides in the presence of 3d-metal acetylacetonates was studied.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”