Application of 14898-67-0. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Ruthenium(III) chloride xhydrate, is researched, Molecular Cl3H2ORu, CAS is 14898-67-0, about Photo-degradation of salicylic acid over ruthenium oxide incorporated titania bifunctional photo-catalyst: An approach for direct cleavage of Caro-O bond via hydro-deoxygenation. Author is Wu, Wen-Chia; Yang, Chung-Sung; Chang, Chi-Chia.
Ruthenium oxide incorporated titania (RIT) photocatalyst, with verified ruthenium oxide ratio, have been prepared for photo-degradation In monitoring the photo-catalytic reaction of salicylic acid over RIT, two degradation steps are observed The first one is the de-carboxylation. The other step is the hydro-deoxygenation. The final product collected from the degradation is benzene. On the basis of exptl. results, the photo-induced e-h pair from the crystalline domain of titania in RIT plays the key role in inducing the de-carboxylation degradation As for the hydro-deoxygenation reaction, the Ru0/ Ru4+ ratio of incorporated ruthenium oxide in RIT is the pivitol factor in the direct cleavage of Caro–O bond of phenol. The best selectivity for Caro–O bond cleavage (71.9%) is shown in the RIT-1, Ru/Ti = 3.53%, route. If the ratio of Ru/Ti reaches to 10.81% (RIT-3), the selectivity decreases to 4.8%.
This literature about this compound(14898-67-0)Application of 14898-67-0has given us a lot of inspiration, and I hope that the research on this compound(Ruthenium(III) chloride xhydrate) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”