Day: February 9, 2023

Modulating the Electronic Metal-Support Interactions in Single-Atom Pt₁-CuO Catalyst for Boosting Acetone Oxidation was written by Jiang, Zeyu;Tian, Mingjiao;Jing, Meizan;Chai, Shouning;Jian, Yanfei;Chen, Changwei;Douthwaite, Mark;Zheng, Lirong;Ma, Mudi;Song, Weiyu;Liu, Jian;Yu, Jiaguo;He, Chi. And the article was included in Angewandte Chemie, International Edition in 2022.Related Products of 20427-59-2 This article mentions the following:

The development of highly active single-atom catalysts (SACs) and identifying their intrinsic active sites in oxidizing industrial hazardous hydrocarbons are challenging prospects. Tuning the electronic metal-support interactions (EMSIs) is valid for modulating the catalytic performance of SACs. We propose that the modulation of the EMSIs in a Pt₁-CuO SAC significantly promotes the activity of the catalyst in acetone oxidation The EMSIs promote charge redistribution through the unified Pt-O-Cu moieties, which modulates the d-band structure of at. Pt sites, and strengthens the adsorption and activation of reactants. The pos. charged Pt atoms are superior for activating acetone at low temperatures, and the stretched Cu-O bonds facilitate the activation of lattice oxygen atoms to participate in subsequent oxidation We believe that this work will guide researchers to engineer efficient SACs for application in hydrocarbon oxidation reactions. In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2Related Products of 20427-59-2).

Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. Copper catalyst has received great attention owing to the low toxicity and low cost. Copper nanoparticles can also catalyze the coupling reaction of nitrogen-containing nucleophiles, phenols, thiols, xanthogenates, selenium ruthenium nucleophiles and the like.Related Products of 20427-59-2

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Crystal facet effect induced by different pretreatment of Cu₂O nanowire electrode for enhanced electrochemical CO₂ reduction to C₂₊ products was written by Fu, Yang;Xie, Qixian;Wu, Linxiao;Luo, Jingshan. And the article was included in Chinese Journal of Catalysis in 2022.Computed Properties of CuH2O2 This article mentions the following:

Electrocatalytic CO₂ conversion has been considered as a promising way to recycle CO₂ and produce sustainable fuels and chems. However, the efficient and highly selective electrochem. reduction of CO₂ directly into multi-carbon (C₂₊) products remains a great challenge. Herein, we synthesized three type catalysts with different morphologies based on Cu₂O nanowires, and studied their morphol. and crystal facet reconstruction during the pre-reduction process. Benefiting from abundant exposure of Cu (100) crystal facet, the nanosheet structure derived Cu catalyst showed a high faradaic efficiency (FE) of 67.5% for C₂₊ products. Addnl., electrocatalytic CO₂ reduction studies were carried out on Cu(100), Cu(110), and Cu(111) single crystal electrodes, which verified that Cu(100) crystal facets are favorable for the C₂₊ products in electrocatalytic CO₂ reduction Our work showed that catalysts would reconstruct during the CO₂ reduction process and the importance in morphol. and crystal facet control to obtain desired products. In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2Computed Properties of CuH2O2).

Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. The applications of Copper-based nanoparticles have received great attention due to the earth-abundant, low toxicity and inexpensive. The copper-mediated C-C, C-O, C-N, and C-S bond formation is a part of one oldest reaction, emphasizing the Ullmann cross-coupling reaction.Computed Properties of CuH2O2

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Microfluidics-Assisted Synthesis of Hierarchical Cu₂O Nanocrystal as C₂-Selective CO₂ Reduction Electrocatalyst was written by Jun, Minki;Kwak, Changmo;Lee, Si Young;Joo, Jinwhan;Kim, Ji Min;Im, Do Jin;Cho, Min Kyung;Baik, Hionsuck;Hwang, Yun Jeong;Kim, Heejin;Lee, Kwangyeol. And the article was included in Small Methods in 2022.Safety of Cuprichydroxide This article mentions the following:

Copper-based catalysts have attracted enormous attention due to their high selectivity for C2+ products during the electrochem. reduction of CO₂ (CO2RR). In particular, grain boundaries on the catalysts contribute to the generation of various Cu coordination environments, which have been found essential for C-C coupling. However, smooth-surfaced Cu₂O nanocrystals generally lack the ability for the surface reorganization to form multiple grain boundaries and desired Cu undercoordination sites. Flow chem. armed with the unparalleled ability to mix reaction mixture can achieve a very high concentration of unstable reaction intermediates, which in turn are used up rapidly to lead to kinetics-driven nanocrystal growth. Herein, the synthesis of a unique hierarchical structure of Cu₂O with numerous steps (h-Cu₂O ONS) via flow chem.-assisted modulation of nanocrystal growth kinetics is reported. The surface of h-Cu₂O ONS underwent rapid surface reconstruction under CO₂RR conditions to exhibit multiple heterointerfaces between Cu₂O and Cu phases, setting the preferable condition to facilitate C-C bond formation. Notably, the h-Cu₂O ONS obtained the increased C₂H₄ Faradaic efficiency from 31.9% to 43.5% during electrocatalysis concurrent with the morphol. reorganization, showing the role of the stepped surface. Also, the h-Cu₂O ONS demonstrated a 3.8-fold higher ethylene production rate as compared to the Cu₂O nanocube. In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2Safety of Cuprichydroxide).

Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. The evolution of transition metal catalysts has attained a stage of civilization that authorizes for an extensive scope of chemical bonds formation partners to be combined efficiently. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Safety of Cuprichydroxide

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Boosting activity of Ni(OH)₂ toward alkaline energy storage by Co and Mn co-substitution was written by Yu, Yawei;Liu, Jiangchuan;Zhang, Yanling;Song, Kefan;Hu, Xiaohui;Zhu, Yunfeng;Hu, Xiulan. And the article was included in Journal of Alloys and Compounds in 2022.Electric Literature of CuH2O2 This article mentions the following:

Ni-based hydroxides nanomaterials are widely used in alk. storage devices. Under the guidance of d. functional theory calculations and exptl. investigations, here, (Ni₀.₈Co₀.₁Mn₀.₁)(OH)₂ is designed and prepared on CuO nanowire arrays, demonstrating Co and Mn co-substitution resulted in enhanced capacity and stability of Ni(OH)₂. The enhanced performance is mainly thanks to the low deprotonation energy and the facile electron transport, which results from the synergistic interactions among Ni, Co and Mn. Ni-Zn battery and alk. hybrid super capacitor with (Ni₀.₈Co₀.₁Mn₀.₁)(OH)₂ (8.4 mg cm^-2) as pos. electrode can achieve infusive energy d. of 605.2 and 270.1 Wh kg^-1, resp. The finding lay a foundation for further the design and fabrication of high-performance Ni-based nanomaterials for alk. energy storage. In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2Electric Literature of CuH2O2).

Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. Copper catalyst has received great attention owing to the low toxicity and low cost. Due to these characteristics, copper nanoparticles have generated a great deal of interest especially in the field of catalysis. Electric Literature of CuH2O2

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

The behavior and mechanism of toxic Pb(II) removal by nanoscale zero-valent iron-carbon materials based on the oil refining byproducts was written by Shi, Yahui;Cheng, Xiaofan;Wan, Dongjin;Zhang, Zhixiang;Chen, Zhaohui;Han, Xinze;Zhou, Qian. And the article was included in Inorganic Chemistry Communications in 2022.Quality Control of Cuprichydroxide This article mentions the following:

In this study, nanoscale zero-valent iron-carbon materials based on the oil refining byproducts (nZVI-SBE@C) were prepared through anoxic pyrolysis and liquid phase reduction method, and its ability to remove Pb(II) from aqueous solution was tested for the first time. In preparation process, when the mass ratio of C/Fe is 1:2, nZVI-SBE@C has the maximum removal capacity of Pb(II) (182.29 mg/g), which is four times that of SBE@C (51.37 mg/g). In the research of Pb(II) removal behavior, adsorption process by nZVI-SBE@C was fitted well with Langmuir isotherm model and pseudo-second-order kinetic model, and the Langmuir monolayer maximum adsorption capacity of nZVI-SBE@C for Pb(II) was 223.52 mg/g. In the N2 and air initial atm., Pb(II) removal reached 95.37% and 42.37%, resp., which were higher than that in blank control group (24.44%). The promotion order of the coexisting cations for nZVI-SBE@C to remove Pb(II) is: Na⁺ > K⁺ > Mg²⁺ (the effect of NO^–₃), and the inhibition order is: Cu²⁺ < Fe³⁺ < Al³⁺ (the effect of the solubility products of precipitation as well as ionic radius). Pb(II) removal by nZVI-SBE@C increased with the increase of initial solution pH (2.30-5.80). Though the characterization of the materials before and after the reaction, meanwhile combining with exptl. data, Pb(II) removal mechanisms of nZVI-SBE@C may include surface adsorption, electrostatic attraction, ion exchange, surface complexation and nZVI reduction (small portion). In the experiment, the researchers used many compounds, for example, Cuprichydroxide (cas: 20427-59-2Quality Control of Cuprichydroxide).

Cuprichydroxide (cas: 20427-59-2) belongs to copper catalysts. The applications of Copper-based nanoparticles have received great attention due to the earth-abundant, low toxicity and inexpensive. Copper of different valence states can be used to catalyze the coupling reaction, especially the Ullmann coupling reaction. Quality Control of Cuprichydroxide

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”