Heterophasic synthesis of bimetallic In hexafluoroacetylacetonate complexes with transition metals was written by Zheleznova, L. I.;Slyusarchuk, L. I.;Trunova, E. K.. And the article was included in Ukrainskii Khimicheskii Zhurnal (Russian Edition) in 2016.SDS of cas: 14781-45-4 This article mentions the following:
Heterometallic hexafluoroacetylacetonate (hfacac) complexes [MIn(hfacac)5] [M = Co(II), Cu(II), Zn] and [NdIn(hfacac)6] were prepared and examined by IR and UV-vis. diffuse reflectance spectra. The method of synthesis of heteronuclear hexafluoroacetylacetonate complexes which is based on the interaction of the metallic indium dissolved in the hexafluoroacetylacetone and acetonitrile medium in the presence of the oxidizing agent (air oxygen) with an oxide or a chloride of transition metal is suggested. The synthesis of the complexes is carried out in the mild conditions without a use of aggressive reagents, high temperatures and special equipment. Novel heterometallic complexes with the composition of MIn(HFA)n·ANm (M – Co(II), Cu(II), Zn(II), Nd(III)) were synthesized. According to IR-spectroscopy, electronic absorption spectra and DTA, it was established that the coordination center of Co(II) and Cu(II) has the structure of distorted octahedron in the complexes with 3d-metals while the neodymium heterometallic complex has C4v symmetry with coordination number 8 for Nd (III). Based on comparison of the thermal anal. for mono- and heteronuclear hexafluoroacetylacetonate it was shown that heterometallic complexes have a wide interval of stability in a gas phase and low sublimation temperatures In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4SDS of cas: 14781-45-4).
copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. The applications of Copper-based nanoparticles have received great attention due to the earth-abundant, low toxicity and inexpensive. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.SDS of cas: 14781-45-4
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”