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The investigation of transient and spectral photovoltage (PV) for charge injection from a dye [Ru(dcbpyH2)2(NCS)2] into transparent hole (CuSCN, CuI, CuAlO2) and electron (TiO2, SnO2:F) conductors was discussed. Depending on the transparent hole or electron conductor and on the mechanism of charge separation, the PV signal rises to a maximum within 10 ns to 10 mus. It was shown that the efficiency of hole and electron injection was of the same order while the effective lifetimes of injected charge vary between several mus and 1 ms for the samples used. It was shown that a 1000 W Xe-lamp with a quartz monochromator provided light in the range of 0.4 to 4.5 eV for PV spectra.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”