But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! Read on for other articles about !, HPLC of Formula: CCuNS
As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, and get your work the international recognition that it deserves. HPLC of Formula: CCuNS, Name is Cuprous thiocyanate, HPLC of Formula: CCuNS, molecular formula is CCuNS. In a article，once mentioned of HPLC of Formula: CCuNS
The salts Cu(CN) and Cu(NCS) react with 2,2′-biquinoline (bq = C18H12N2) to give the adducts <n> (1) and <n> (2).Complex (1) crystallyzes in space group C2/m with cell dimensions a = 13.626(2), b = 15.322(2), c = 7.908(1) Angstroem, beta = 95.89(1) deg, and Z = 2.It consists of chains of CN-bridged copper atoms, each copper being either linearly or tetrahedrally co-ordinated.The tetrahedral copper is also co-ordinated to bq.Pairs of bq molecules belonging to paralell chains stack with an interplanar spacing of 3.35 Angstroem.Complex (2) is microcrystalline and from hot dimethyl sulphoxide gives crystals of (3).The polarization properties of the i.r. and electronic bands of complex (1) have been determined.In the optical spectrum two metal-to-ligand charge-transfer transitions could be detected.Comparison of the spectroscopic properties of the three compounds indicates a lower degree of polymerization for (3).
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! Read on for other articles about !, HPLC of Formula: CCuNS
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”