In heterogeneous catalysis, the catalyst is in a different phase from the reactants. SDS of cas: 1111-67-7, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 1111-67-7, name is Cuprous thiocyanate. In an article£¬Which mentioned a new discovery about 1111-67-7
A single-helix copper-containing coordination polymer of dihydroglyoxaline sulfide formed in situ through oxidation of 1,3-imidazolidine-2-thione
A novel single-stranded helix coordination polymer [Cu(L)(SO4)(H2O)] (L = dihydroglyoxaline sulfide) was synthesized and characterized by single-crystal X-ray diffraction, IR, and TGA analysis. The polymer is an unprecedented 1D helical polymer based on a sulfate bridge and a dihydroglyoxaline sulfide chelating ligand. Both ligands were formed in situ through copper-mediated oxidation of 1,3-imidazolidine-2-thione. The helical chain is interlocked with each other through strong hydrogen bonding interactions to form a 2D sheet, which then stacks together to generate a 3D hydrogen bonding network.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”