Related Products of 16606-55-6, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 16606-55-6, Name is (R)-4-Methyl-1,3-dioxolan-2-one, SMILES is O=C1OC[C@@H](C)O1, belongs to copper-catalyst compound. In a article, author is Zang, Dejin, introduce new discover of the category.
Interface engineering of Mo-8/Cu heterostructures toward highly selective electrochemical reduction of carbon dioxide into acetate
Electrocatalytic CO2 reduction reaction (CO2RR) is a promising pathway for storage of renewable electricity and converting CO2 into value-added products. It’s highly desired to obtain acetic acid via CO2RR since it’s an important chemical feedstock and high energy-density liquid fuel. However, developing highly efficient elec-trocatalysts for selective CO2RR toward acetate remains formidable challenge. We report an interface engineering strategy to modify copper nanocubes with polyoxometalate (POM) to generate Cu-O-Mo interface as active sites for CO2RR, achieving state-of-the-art activity with 48.68% acetate formation Faradaic efficiency and current density of similar to 110 mA cm(-2) at-1.13 V vs RHE. DFT calculations suggest the interface of Cu planes and polyoxometalate clusters with abundant Cu-O-Mo active sites promote the generation of *CH3 and successive coupling with CO2 insertion, showing a potential dependence of acetate production. This work provides a Cu-O-Mo interface model for the rational design of earth-abundant metal based electrocatalysts for CO2RR and other renewable energy conversions.
Related Products of 16606-55-6, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 16606-55-6 is helpful to your research.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”