Chemistry, like all the natural sciences, begins with the direct observation of nature¡ª in this case, of matter.14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, SMILES is OC[C@H]1OC(C)(C)OC1, belongs to copper-catalyst compound. In a document, author is Ding, Yangyang, introduce the new discover, COA of Formula: C6H12O3.
Cu-doped Ni3S2 Interlaced Nanosheet Arrays as High-efficiency Electrocatalyst Boosting the Alkaline Hydrogen Evolution
Ni3S2 has been widely reported as an effective electrochemical catalyst for hydrogen evolution reaction (HER). However, the electrochemical activity of the cathode reduction reaction needs to be further improved due to the drawback of strong S-H bond interaction on the surface of Ni3S2. Herein, a series of non-precious metal Cu element doped Ni3S2 materials were prepared on the Nickel foam support (Cu-Ni3S2/NF) though a two-step hydrothermal method. Moreover, we optimized the performance of the catalyst by adjusting the molar amount of doped copper ion in the first hydrothermal process. When the molar ratio of copper ion and nickel ion is 1 : 4, the Cu-Ni3S2/NF-1/4 material with independent and clustered rose-shaped cross-nanosheet arrays structure have been used as a highly efficient electrochemical hydrogen evolution reaction (HER) catalyst. In HER process, the Cu-Ni3S2/NF-1/4 material drives the current densities of 10 mA cm(-2) and 50 mA cm(-2) under low overpotentials of 92 mV and 256 mV respectively, while Ni3S2/NF needs 210 mV and 397 mV to reach the same current densities. Density functional theory (DFT) calculation shows that the superior electrocatalytic activities are attributed to optimized water adsorption energy and enhanced electrical conductivity. The stability of catalyst was tested in 1 M KOH for 12 hours by chronoamperometry, indicating the current density has no an apparent attenuation.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 14347-78-5. COA of Formula: C6H12O3.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”