Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 16606-55-6, Name is (R)-4-Methyl-1,3-dioxolan-2-one, SMILES is O=C1OC[C@@H](C)O1, in an article , author is Mishra, Subhashree, once mentioned of 16606-55-6, Quality Control of (R)-4-Methyl-1,3-dioxolan-2-one.
Heterogeneous recyclable copper oxide supported on activated red mud as an efficient and stable catalyst for the one pot hydroxylation of benzene to phenol
Phenol is a key intermediate in chemical industry. The present research work reports facile synthesis of a new copper supported activated red mud as a heterogeneous catalyst for oxidative conversion of benzene to phenol. The process is simple and efficient for one pot hydroxylation reaction using H2O2 as an oxidant. The catalyst was characterized using FTIR, XRD, TEM, XPS and BET surface area analyzer. Catalyst reducible properties were studied using H-2-TPR technique. The one-pot hydroxylation reaction, carried out at 75 degrees C under optimum reaction conditions in presence of catalytic material, shows conversion of benzene to phenol with 84.5 % and 87.1 % selectivity and conversion efficiency, respectively. The proposed mechanism emphasizes upon cooperative effect of residual and embedded metal ions in solid catalyst matrix as the contributing factor for efficient conversion and selectivity. The reusable properties of the material, tested up to 5th consecutive cycles of batch operation, indicate retention of selectivity (83.9 %) as well as conversion efficiency (86.7 %), suitable for future commercial development adhering to the principle of green chemistry.
Interested yet? Read on for other articles about 16606-55-6, you can contact me at any time and look forward to more communication. Quality Control of (R)-4-Methyl-1,3-dioxolan-2-one.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”