In an article, author is Balciunaite, A., once mentioned the application of 16606-55-6, Name: (R)-4-Methyl-1,3-dioxolan-2-one, Name is (R)-4-Methyl-1,3-dioxolan-2-one, molecular formula is C4H6O3, molecular weight is 102.09, MDL number is MFCD00798265, category is copper-catalyst. Now introduce a scientific discovery about this category.
Investigation of hydrogen generation from sodium borohydride using different cobalt catalysts
Effective Co/Cu, CoB/Cu, and CoBM (M = Mo,Zn,Fe)/Cu catalysts were prepared on the copper surface by a simple electroless deposition method using a morpholine borane as a reducing agent in the glycine solution. The activity of the deposited catalysts was investigated for hydrogen generation from an alkaline sodium borohydride solution. It was determined that these synthesized catalysts demonstrated the catalytic activity for the hydrolysis reaction of NaBH4. The lowest obtained activation energy (EA) of the hydrolysis reaction of NaBH4 was 27 kJ mol(-1) for the CoBMo/Cu catalyst. The hydrogen generation rate of 15.30 ml min(-1) was achieved using CoBMo/Cu catalysts at 313 K and it increased similar to 3.5 times with the increase of temperature to 343 K. The highest hydrogen generation rate obtained by CoBMo/Cu films may be related to the hierarchical cauliflower-shaped 3D structures and the high roughness surface area. Moreover, the CoBMo/Cu catalyst showed an excellent reusability. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”