In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. HPLC of Formula: CCuNS. Introducing a new discovery about 1111-67-7, Name is Cuprous thiocyanate
Synthesis, structures, luminescence and terahertz time-domain spectroscopy of nine Cu(I) complexes with P^P ligands and 1,10-phenanthroline derivatives
Nine new copper(I) complexes bearing 1,3-bis(diphenylphosphino)propane (dppp) and 4,7-diphenyl-1,10-phenanthroline (batho) or 2,9-dimethyl-1,10-phenanthroline (neo) have been synthesized and characterized. Single crystal X-ray diffraction analysis reveals that complexes 1?4 and 6?9 are mononuclear with similar structures, while complex 5 is a binuclear structure. They display absorption around 280 nm and 410 nm, and the intensive emission in the range of 520?620 nm in the solid state occurring with lifetimes on the mus timescale indicates phosphorescence. Our TD-DFT calculations show that emission from the lowest excited triplet state T1 is of 3MLCT nature. This study manifests that these simple and long-lifetime Cu(I) systems may exhibit a similar, but more complex excited state behavior than the systems previously appreciated.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”