Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, SDS of cas: 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. SDS of cas: 1111-67-7In an article, authors is Hu, Bin, once mentioned the new application about SDS of cas: 1111-67-7.
Four pairs of transition-metal [Co(II), Zn(II), Ni(II) and Cu(I)] coordination polymers have been prepared and characterized based on a pair of isomeric linear and V-shaped rigid thiophene-centered ditriazole bridging ligands [2,5-di(1H-1,2,4-triazol-1-yl)thiophene (L1) and 3,4-di(1H-1,2,4-triazol-1-yl)thiophene (L2)]. They are formulated as {[Co(L1)2(H2O)2](ClO4)2}n (1), {[Zn(L1)2(H2O)2](ClO4)2}n (2), {[Ni(L1)2(H2O)2](ClO4)2}n (3), {[Co(L2)2(H2O)2](ClO4)2}n (4), {[Zn(L2)2(H2O)2](ClO4)2}n (5), {[Ni(L2)2(H2O)2](ClO4)2}n (6), [Cu(L1)(CN)]n (7) and [Cu2(L2)(SCN)2]n (8), where distinct metal/ligand ratios (1:2, 1:1 and 2:1) and dimensions [one-dimensional (1D), two-dimensional (2D) and three-dimensional (3D)] have been observed because of the alterations of the coordination modes of central metal ions, the shape and conformation of ligands and the participancy of counterions. X-ray single-crystal diffraction analyses reveal that 1D chains have been formed in the cases of 4-6, while 2D planes have been built in 1-3. In contrast, 3D networks have been constructed in 7 and 8 with different topologies because of the further linkage of CN- and SCN- counterions.
Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 1111-67-7 is helpful to your research.
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”