Related Products of 13395-16-9, Chemistry is a science major with cience and engineering. The main research on the structure and performance of functional materials.Mentioned the application of 13395-16-9, Name is Bis(acetylacetone)copper.
We have created a facial self-templated method to synthesize three distinct nanostructures, including the unique edge-cut Cu@Ni nanocubes, edge-notched Cu@Ni nanocubes, and mesoporous Cu-Ni nanocages by selective wet chemical etching method. Moreover, in the synthesis process, the corners of edge-cut Cu@Ni nanocubes and mesoporous Cu-Ni nanocages can be etched to produce the highly catalytically active (111) facets. Impressively, compared to edge-notched Cu@Ni nanocubes and edge-cut Cu@Ni nanocubes, the Cu-Ni nanocages exhibit higher electrocatalytic activity in the hydrogen evolution reaction (HER) under alkaline conditions. When obtained overpotential is 140 mV, the current density can reach 10 mA cm-2 meanwhile, the corresponding Tafel slope is 79 mV dec-1. Moreover, from the calculation results of density functional theory (DFT), it can be found that the reason why the activity of pure Ni is lower than that of Cu-Ni alloy is that the adsorption energy of the intermediate state (adsorbed H?) is too strong. Meanwhile the Gibbs free-energy (|DeltaGH?|) of (111) facets is smaller than that of (100) facets, which brings more active sites or adsorbs more hydrogen.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 13395-16-9 is helpful to your research. Related Products of 13395-16-9
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”