As a common heterocyclic compound, it belong copper-catalyst compound,5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II),14172-91-9,Molecular formula: C44H30CuN4,mainly used in chemical industry, its synthesis route is as follows.,14172-91-9
General procedure: To a solution of corresponding porphyrin, the copper complex(1.13 mmol) in methylene chloride (90 mL) Cu(NO3)2¡¤3H2O(2.30 mmol) in the mixture of acetic acid (5 mL) and acetic anhydride (2 mL) was added, and reaction mixture was stirred for 3 h at room temperature, with TLC monitoring (CHCl3-hexane 1:2). After completion of the reaction the solution was washed with water (200 mL), then with Na2CO3 solution, and the organic phase was separated and dried over Na2SO4. After removal of the solvent under reduced pressure, the residue was purified by column chromatography on silica gel using a CH2Cl2-hexane system (3:7).
With the synthetic route has been constantly updated, we look forward to future research findings about 5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II),belong copper-catalyst compound
Reference£º
Article; Ol’shevskaya, Valentina A.; Alpatova, Viktoriya M.; Radchenko, Alexandra S.; Ramonova, Alla A.; Petrova, Albina S.; Tatarskiy, Victor V.; Zaitsev, Andrei V.; Kononova, Elena G.; Ikonnikov, Nikolay S.; Kostyukov, Alexey A.; Egorov, Anton E.; Moisenovich, Mikhail M.; Kuzmin, Vladimir A.; Bragina, Natalya A.; Shtil, Alexander A.; Dyes and Pigments; vol. 171; (2019);,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”