Quality Control of Cuprous thiocyanate, Some examples of the diverse research done by chemistry experts include discovery of new medicines and vaccines, improving understanding of environmental issues, and development of new chemical products and materials. In an article,authors is Szpakolski, Katherine B., once mentioned the application of Quality Control of Cuprous thiocyanate, Name is Cuprous thiocyanate, is a conventional compound.
Complexes containing di(2-pyridyl) ketone (dpk) as a bi- (N,N) and tridentate (N,N,O) ligand have been synthesised1,2 and characterized by spectral and structural studies. Products 1 and 2 are polymorphs of the polymeric copper(I) complex [Cu(dpk)(NCS)]n containing dpk with thiocyanate anions which bridge to form a one-dimensional continuous polymer chain. The novel dinuclear copper(II) complex [Cu2(dpkA·acetone) 2(NCS)2] (3) was formed when 1 and 2 were allowed to stand in the supernatant. In this instance it appears that a transition-metal- promoted aldol condensation has occurred between the solvent acetone and the ketone carbonyl of dpk to produce the novel ligand, dpkA·acetone. Product 3 contains two five-coordinate copper(II) ions, both with trigonal bipyramidal coordination, bridged through deprotonated hydroxy groups on each dpkA·acetone. A chemical rationalisation for the formation of 3 is proposed. The dinuclear copper(I) complex [Cu2(dpk)2I 2] (4) is also reported, which contains two four-coordinate copper(I) ions that are bridged together through iodide ions.
The catalyzed pathway has a lower Ea, but the net change in energy that results from the reaction is not affected by the presence of a catalyst. In my other articles, you can also check out more blogs about 1111-67-7
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”