Nizel’skii, Yu. N. published the artcileRole of alcohol self-association in the kinetics of urethane formation catalyzed by copper β-diketonates, Recommanded Product: Copper(II) ethylacetoacetate, the publication is Zhurnal Organicheskoi Khimii (1980), 16(3), 495-505, database is CAplus.
Kinetic and spectral studies indicated that the bis(Et acetoacetato)copper (I)-catalyzed reaction of PhNCO with excess MeOH involved complexation of I with the monomeric and self-associated alc. The associated alc. was more reactive than the monomer in both the catalytic and noncatalytic processes. The activation parameters showed that the transition-state structure played an important role in the acceleration of the reaction.
Zhurnal Organicheskoi Khimii published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Recommanded Product: Copper(II) ethylacetoacetate.
Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”