Maruyama, Kazuhiro’s team published research in Chemistry Letters in | CAS: 14284-06-1

Chemistry Letters published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Synthetic Route of 14284-06-1.

Maruyama, Kazuhiro published the artcileCopper(II)-catalyzed cyclization of azidoalkadienylquinones. Stereoselective formation of dihydropyrroloindoloquinones and the related quinolinoquinone, Synthetic Route of 14284-06-1, the publication is Chemistry Letters (1987), 97-100, database is CAplus.

Azidoalkadienylquinones (e.g., I; n = 1,2) cyclized in the presence of Cu(acac)2 (acac = acetylacetonate) to stereoselectively give up to 48% dihydropyrroloindolediones and -quinolinediones (e.g., II; n = 1,2). In the absence of Cu(acac)2 cyclization did not occur. Evaluation of other metal salts and ligands showed Cu(acac)2 had the best catalytic activity.

Chemistry Letters published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, Synthetic Route of 14284-06-1.

Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”