Journal of Macromolecular Science, Chemistry published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, COA of Formula: 0.
Mun, Yangun published the artcileMetal-containing initiator systems. XXXVI. Synthesis of block copolymer of methyl acrylate and α-methylbenzyl methacrylate with binary initiator system of cobaltocene and bis(ethyl acetoacetato)copper(II), COA of Formula: 0, the publication is Journal of Macromolecular Science, Chemistry (1984), A21(11-12), 1535-46, database is CAplus.
Block copolymerization of Me acrylate (I) and (DL)-α-methylbenzyl methacrylate (II) with a cobaltocene [1277-43-6]-Cu(AcCH2CO2Et)2 [14284-06-1] initiator system at 25° in MeCN was studied. The mol. weight of I polymer [9011-14-7] increased with time in the early stages of polymerization Although II polymer [25085-84-1] was also prepared, asym. selective polymerization was not induced by the presence of (-)-sparteine. I–II block copolymer [92542-26-2] was prepared in up to 90% yield. I–II block copolymer yield depended on the prepolymerization time of I with this system. The block copolymer was characterized by IR, NMR, and gel-permeation chromatog.
Journal of Macromolecular Science, Chemistry published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, COA of Formula: 0.
Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”