Kondratov, S. A. published the artcileCatalysis by copper complexes in the reaction of o-nitrochlorobenzene with ammonia, HPLC of Formula: 14284-06-1, the publication is Kinetika i Kataliz (1980), 21(5), 1232-7, database is CAplus.
π-Acceptor ligands having no reducing properties (e.g., 2,2′-bipyridine, 8-quinolinol) lower the catalytic activity of Cu2+ in the title reaction. π-Acceptor ligands with reducing properties (e.g., β-diketones, amino acids) reduce Cu2+ to Cu+ and cause a 15-20-fold increase in the initial rate, although reductive dechlorination occurs as a side reaction. Donor ligands (e.g., ethylenediamine) show a small effect on the activity of Cu2+. The title reaction in the presence of CuCl, Cu bis(acetylacetonate) (I) and Cu diglycinate (II) is 1st order in substrate and catalyst. In the case of I the reaction is 0.42 order in NH3; in the case of II it is zero order in NH3.
Kinetika i Kataliz published new progress about 14284-06-1. 14284-06-1 belongs to copper-catalyst, auxiliary class Copper, name is Copper(II) ethylacetoacetate, and the molecular formula is 0, HPLC of Formula: 14284-06-1.
Referemce:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660968/,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”