Reactivity of a formal Cu(III)-alkyl species toward aniline: a DFT investigation was written by Xu, Xinyu. And the article was included in Dalton Transactions in 2020.Product Details of 14781-45-4 This article mentions the following:
Although formal Cu(III) species were extensively proposed as key intermediates in a wide range of Cu-catalyzed reactions, the precise reactivity of these species remains inconclusive. Commonly, a formal reductive elimination mechanism is proposed for the product formation step. Through theor. study of the reactivity between a formal Cu(III)-alkyl species and aniline, a SN2-like mechanism could also be responsible for coupling product formation. In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4Product Details of 14781-45-4).
copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. The transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents has turned up as an exceedingly robust synthetic tool. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Product Details of 14781-45-4
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”