Coordination Chemistry of 2,2′-Bipyridyl- and 2,2′:6′,2”-Terpyridyl-Substituted BEDT-TTFs: Formation of a Supramolecular Capsule Motif by the Iron(II) Tris Complex of 2,2′-Bipyridine-4-thiomethyl-BEDT-TTF was written by Wang, Qiang;Martin, Lee;Blake, Alexander J.;Day, Peter;Akutsu, Hiroki;Wallis, John D.. And the article was included in Inorganic Chemistry in 2016.Recommanded Product: 14781-45-4 This article mentions the following:
Mols. of tris(2,2′-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramol. capsular structure in the solid state. Three BEDT-TTF residues from one complex lie in the three grooves between coordinated bipyridines of the other complex, and vice versa, to form a capsule with 3-fold rotational symmetry and an internal volume of ∼160 Å3. Further aspects of the coordination chem. of this ligand, its 6-substituted isomer, and the 2,2′:6’2”-terpyridyl-4′-thiomethyl-BEDT-TTF analog are described, [M(Ln)3](PF6)2 and [M(L2)(hfac)2] , where M = Zn, Mn, Fe, Co, Ni, or Cu, Ln = bipyridines terpyridine substituted tetrathiafulvalenes, and hfac = hexafluoroacetylacetonato. In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4Recommanded Product: 14781-45-4).
copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. Copper catalyst has received great attention owing to the low toxicity and low cost. These ligands enable the reaction promoted in mild condition. The reaction scope has also been greatly expanded, rendering this copper-based cross-coupling attractive for both academia and industry. Recommanded Product: 14781-45-4
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”