Synthesis and reactions of N-heterocycle functionalised variants of heterometallic {Cr7Ni} rings was written by Whitehead, George F. S.;Ferrando-Soria, Jesus;Carthy, Laura;Pritchard, Robin G.;Teat, Simon J.;Timco, Grigore A.;Winpenny, Richard E. P.. And the article was included in Dalton Transactions in 2016.Related Products of 14781-45-4 This article mentions the following:
Here the authors present a series of linked cage complexes of functionalized variants of the octametallic ring {Cr7Ni} with the general formula [Pr2NH2][Cr7NiF8(O2CtBu)15(O2CR)], where HO2CR is a N-heterocycle containing carboxylic acid. These compounds are made by reacting [Pr2NH2][Cr7NiF8(O2CtBu)15(O2CR)] with a variety of simple metal salts and metal dimers. The carboxylic acids studied include iso-nicotinic acid, 3-(4-pyridyl)acrylic acid and 4-pyridazine carboxylic acid. These new linked cage complexes have been studied structurally and the study highlights the versatility of functionalized {Cr7Ni} as a Lewis base ligand. As {Cr7Ni} is a putative mol. electron spin qubit this work contributes to the authors’ understanding of the chem. that might be required to assemble mol. spin qubits. In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4Related Products of 14781-45-4).
copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. Transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents belong to the most important cross-coupling reaction in organic synthesis. The copper-mediated C-C, C-O, C-N, and C-S bond formation is a part of one oldest reaction, emphasizing the Ullmann cross-coupling reaction.Related Products of 14781-45-4
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”