A reaction-dissolution strategy for designing solid electrolyte interphases with stable energetics for lithium metal anodes was written by Biswal, Prayag;Rodrigues, Joshua;Kludze, Atsu;Deng, Yue;Zhao, Qing;Yin, Jiefu;Archer, Lynden A.. And the article was included in Cell Reports Physical Science in 2022.Recommanded Product: 34946-82-2 This article mentions the following:
The spatial variations in chem. composition and transport properties of the interphase formed on reactive metal electrodeposits dictate the stability and reversibility of electrochem. cells that use reactive metals as anodes. Here we report on the influence of carbonate and fluorinated electrolytes infused with ethers as additives on the phys.-chem. characteristics and reversibility of metallic lithium (Li) during early stages of electrodeposition and later stages of deep cycling of Li metal anodes. We show that a feasible strategy for achieving and sustaining kinetically enhanced interphases through the cycle life of Li electrodeposits is by simultaneous use of sacrificial electrolyte components that undergo electroreduction to enrich the interphase with fluorinated species in tandem with cleaning electrolyte components that promote dissolution and removal of less desirable carbonaceous compounds We demonstrate that this approach translates to high electrochem. reversibility during deep cycling of the Li metal anode and improved performance of Li metal batteries. In the experiment, the researchers used many compounds, for example, Copper(II) trifluoromethanesulfonate (cas: 34946-82-2Recommanded Product: 34946-82-2).
Copper(II) trifluoromethanesulfonate (cas: 34946-82-2) belongs to copper catalysts. The applications of Copper-based nanoparticles have received great attention due to the earth-abundant, low toxicity and inexpensive. These ligands enable the reaction promoted in mild condition. The reaction scope has also been greatly expanded, rendering this copper-based cross-coupling attractive for both academia and industry. Recommanded Product: 34946-82-2
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”