Application of 13395-16-9, One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time.Mentioned the application of 13395-16-9.
Vinylogous Wolff Rearrangement of Cyclic beta,gamma-Unsaturated Diazomethyl Ketones: a New Synthetic Method for Angularly Functionalised Polycyclic Systems
Decomposition of the rigid polycyclic beta,gamma-unsaturated diazomethyl ketones (1a) and (1b) and (2a) and (2b) promoted by ‘activated CuO’, Cu(acac)2, Cu(OTf)2, or Ni(acac)2 in the presence of methanol are shown to give mainly the corresponding rearranged gamma,delta-unsaturated angularly substituted esters (3a) and (3b) and (8a) and (8b) together with the alpha-methoxy ketones (4a) and (4b) and (9a) and (9b).While photo-Wolff rearrangement of the diazo ketones leads to the corresponding homologous esters (5a) and (5b) and (10a) and (10b) the silver benzoate-triethylamine induced reaction gives the rearranged esters in addition to the homologous esters.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”