Reference of 13395-16-9, In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.In an article, once mentioned the application of 13395-16-9, Name is Bis(acetylacetone)copper, is a conventional compound.
We report the cyclohexene oxidation by molecular oxygen in the presence of several metal beta-diketonates. The catalytic conditions used showed an allylic/vinilic oxidation (ao/av) ratio equal 1.5. The complexes M(l)n were used with the metal ions Co(III), Ni(II), Pd(II), Cu(II), chelated with acetylacetone (AcAc), benzoylacetone (BeAc) and dibenzoylacetone (BeBe) as ligands. The oxidation selectivity of the studied system suggests a different allylic/vinylic pathway compared with that observed inprevious reports.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”