HPLC of Formula: 676525-77-2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Dialkylation of 1,3-Dienes by Dual Photoredox and Chromium Catalysis. Author is Schwarz, J. Luca; Huang, Huan-Ming; Paulisch, Tiffany O.; Glorius, Frank.
The direct conversion of feedstock chems. into value-added products is of broad interest in chem. research. Herein, we present a regioselective and diastereoselective three-component dialkylation of feedstock 1,3-dienes with Hantzsch esters and aldehydes for the synthesis of homoallylic alcs. The reaction is enabled by dual photoredox and chromium catalysis and can also be performed enantioselectively by employing chromium-bisoxazoline complexes.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”