Archives for Chemistry Experiments of Cuprous thiocyanate

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Syntheses, structures, and luminescence properties of two copper(I) thiocyanate coordination polymers with different N-donor ligands

Two coordination polymers, [Cu(SCN)(3-ptz)]n(1) and [Cu(SCN)(btmb)]n¡¤nCH3CN (2) (3-ptz = 5-(3-pyridyl)tetrazole, btmb = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene), were synthesized and characterized by EA, IR, PXRD and thermogravimetry. Complex 1 is a 2-D coordination polymer constructed from bidentate 3-ptz and 1,3-thiocyanate ligands. Complex 2 is a 2-D wave-like coordination polymer assembled by bidentate btmb and 1,3-thiocyanate ligands. Acetonitrile guest molecule is perched in the tunnel. Complexes 1 and 2 remain stable up to 240C and 280C, respectively. Complex 1 emits strong orange luminescence at 590 nm, and complex 2 emits blue luminescence at 468 nm.

Because enzymes can increase reaction rates by enormous factors and tend to be very specific, category: copper-catalyst, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about category: copper-catalyst

Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”