Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Wang, Wenjie, once mentioned the application of 14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, molecular formula is C6H12O3, molecular weight is 132.1577, MDL number is MFCD00003213, category is copper-catalyst. Now introduce a scientific discovery about this category, Formula: C6H12O3.
Unraveling electrochemical CO reduction of the single-atom transition metals supported on N-doped phosphorene
Electrocatalytic conversion of carbon monoxide (CO) sensitively depends on the activity of catalysts. Although some catalysts have been reported in previous studies, it remains a grand challenge to develop low cost but highly active electrocatalysts for CO reduction with high selectivity. Inspired by single atom metal-nitrogen-graphene catalysts, we theoretically explored the single atom metal-nitrogen-phosphorene catalysts MN3@P (P: monolayer black phosphorus, N: nitrogen atom, M = Mo, Mn, Fe, Co, Cr, Ru, Rh, Pt, Pd, V, and W) for the CO electrochemical reduction by the means of first-principle calculations. Two efficient catalysts, MoN3@P (limiting potential U-L = -0.31 V) and MnN3@P (U-L = -0.59 V) for methane (CH4) product of the CO reduction reaction, are identified for the first time. In particular, the U-L on MoN3@P is significantly less negative than that of -0.74 V for CH4 product of Carbon dioxide (CO2) reduction reaction on copper catalysts Cu(211). This remarkable low U-L originates from the unique pi bonding interaction near Fermi level between the 2p orbital of C atom in adsorbate *CO and 4d orbital of Mo atom in MoN3@P. Furthermore, MoN3@P and MnN3@P are expected to be long-term catalysts because of excellent kinetic stabilities.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 14347-78-5, Formula: C6H12O3.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”