The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.category: copper-catalyst, Name is Bis(acetylacetone)copper, molecular formula is C10H16CuO4, category: copper-catalyst. In a Article, authors is Berezin£¬once mentioned of category: copper-catalyst
Reactions of chelates with macrocyclic ligands. Complexation between tetraphenylporphine and Cu(II) complexes with alpha-amino acids
The reactions of tetraphenylporphine (H2TPP) with copper(II) chelates in DMSO were studied. alpha-Amino acids (glycine, alpha-alanine, valine, leucine, tyrosine, and glutamine) were used as chelating ligands. The study of the reaction kinetics showed that Cu(II) chelates with alanine and the other amino acids are less reactive in these reactions than acetylacetonates, alpha-nitroso-beta-naphtholates, and hydroxyquinolates. The exception is a Cu(II) complex with tyrosine. The relationship between the structure of the above chelates and the rate of their reactions with porphyrin was determined.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”