1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. Quality Control of Cuprous thiocyanateIn an article, once mentioned the new application about 1111-67-7.
From encapsulation to polypseudorotaxane: Unusual anion networks driven by predesigned metal bis(terpyridine) complex cations
Solvothermal reactions of CuSCN, metal (Mn2+, Fe2+, Co2+, Ni2+, Cu2+) sulfate, and terpyridine (2,2?:6?,2?-terpyridine or 4?-p-tolyl-2,2?: 6?,2?-terpyridine) in the presence of triphenylphosphine yielded a series of hybrid coordination compounds, in which in situ formed metal bis(terpyridine) complex cations are encapsulated by a 3D anionic network or entangled by 2D heartlike networks, forming encapsulation or polypseudorotaxane supramolecules. The complex cations play a role as template to direct the fabrication of the structures.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”