Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. Formula: CCuNS, Name is Cuprous thiocyanate, Formula: CCuNS, molecular formula is CCuNS. In a article，once mentioned of Formula: CCuNS
Reactions of (Et4N)[Tp*WS3] [Tp*is hydridotris(3,5-di-methyl-pyrazol-1-yl)borate] with CuSCN in MeCN in the presence of melamine afforded the title neutral dimeric cluster [Cu 4W2(C15H22BN6) 2(NCS)2S6(C2H3N) 2] or [Tp*W(2-S)2(3-S)Cu(2-SCN)(CuMeCN)]2, which has two butterfly-shaped [Tp*WS3Cu2] cores bridged across a centre of inversion by two (CuSCN)- anions. The S atoms of the bridging thio-cyanate ligands inter-act with the H atoms of the methyl groups of the Tp*units of a neighbouring dimer to form a C-H…S hydrogen-bonded chain. The N atoms of the thio-cyanate anions inter-act with the H atoms of the methyl groups of the Tp*units of neighbouring chains, affording a two-dimensional hydrogen-bonded network.
The catalyzed pathway has a lower Ea, but the net change in energy that results from the reaction is not affected by the presence of a catalyst. In my other articles, you can also check out more blogs about 1111-67-7
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”