Awesome Chemistry Experiments For 1111-67-7

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Electric Literature of 1111-67-7, Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 1111-67-7, Name is Cuprous thiocyanate,introducing its new discovery.

Syntheses, topological analyses and photoelectric properties of Ag(I)/Cu(I) metal-organic frameworks based on a tetradentate imidazolate ligand

A new tetradentate imidazolate ligand 1,1?,1?,1???-(2,2?,4,4?,6,6?-hexamethylbiphenyl-3,3?,5,5?-tetrayl)tetrakis(methylene)(1H-imidazole) (L) and four Ag(I)/Cu(I) coordination polymers, namely [(MCN)3L]n (1: M=Ag; 2: M=Cu), and [(MSCN)2L]n (3: M=Ag; 4: M=Cu) are described. All four new coordination polymers were fully characterized by infrared spectroscopy, elemental analysis and single-crystal X-ray diffraction. Compound 1 features a 3D supramolecular framework constructed by 1D chains through inter-chain Ag-N(CN) and inter-layer Ag-N(L) weak interactions with an uninodal 66 topology. Complex 2 presents a 3D framework characterized by a tetranodal (3,4)-connected (3¡¤4¡¤5¡¤102¡¤11)(3¡¤4¡¤5¡¤6¡¤7¡¤9)(3¡¤6¡¤7)(6¡¤102) topology. Complexes 3 and 4 are isostructural, and both have a 3D network of trinodal 4-connected (4¡¤85)2(42¡¤82¡¤102)(42¡¤84)2 topology. The luminescent properties for these compounds in the solid state as well as the possible ferroelectric behavior of 1 are discussed.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”