Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. Safety of Cuprous thiocyanate, Name is Cuprous thiocyanate, molecular formula is CCuNS, Safety of Cuprous thiocyanate, In a Article, authors is Artemev, Alexander V.£¬once mentioned of Safety of Cuprous thiocyanate
Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers
Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N?,N??-Py3P=O)(NCS)], dinuclear (N,N?-Py3P=O)Cu(SCNNCS)Cu[(N,N?-Py3P=O)], their co-crystal (2?:?1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N?,N??-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(i) thiocyanate complexes supported by tripodal ligands.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”