While the job of a research scientist varies, most chemistry careers in research are based in laboratories, where research is conducted by teams following scientific methods and standards. 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. Application In Synthesis of Cuprous thiocyanateIn an article, once mentioned the new application about 1111-67-7.
The reaction of copper(I) iodide with 1, 3-imidazolidine-2-thione (SC 3H6N2) in a 1:2 molar ratio (M/L) has formed unusual 1D polymers, {Cu6(mu3-SC3H 6N2)4(mu-SC3H6N 2)2(mu-I)2I4}n (1) and {Cu6(mu3-SC3H6N2) 2(mu-SC3H6N2)4(mu-I) 4I2}n (1a). A similar reaction with copper(I) bromide has formed a polymer {Cu6(mu3-SC 3H6N2)2(mu-SC3H 6N2)4(mu-Br)4Br2} n (3a), similar to 1a, along with a dimer, {Cu2(mu- SC3H6N2)2(eta1-SC 3H6N2)2Br2} (3). Copper(I) chloride behaved differently, and only an unsymmetrical dimer, {Cu2(mu-SC3H6N2) (eta1-SC3H6N2)3Cl 2} (4), was formed. Finally, reactions of copper-(I) thiocyanate in 1:1 or 1:2 molar ratios yielded a 3D polymer, {Cu2(mu-SC 3H6N2)2(mu-SCN)2} n (2). Crystal data: 1, C9H18Cu 3I3N6S3, triclinic, P1, a = 9.6646(11) A, b = 10.5520(13) A, c = 12.6177(15) A, alpha = 107.239(2), beta = 99.844(2), gamma = 113.682(2), V = 1061.8(2) A3, Z = 2, R = 0.0333; 2, C4H 6CuN3S2, monoclinic, P21/c, a = 7.864(3) A, b = 14.328(6) A, c = 6.737(2) A, beta = 100.07(3), V = 747.4(5), Z = 4, R = 0.0363; 3, C12H 24Br2Cu2N8S4, monoclinic, C2/c, a = 19.420(7) A, b = 7.686(3) A, c = 16.706(6) A, beta = 115.844(6), V = 2244.1(14) A3, Z = 4, R = 0.0228; 4, C12H24Cl2Cu2N8S 4, monoclinic, P21/c, a = 7,4500(6) A, b = 18.4965(15) A, c = 16.2131(14) A, beta = 95.036(2), V = 2225.5(3) A3, Z = 4, R = 0.0392. The 3D polymer 2 exhibits 20-membered metallacyclic rings in its structure, while synthesis of linear polymers; 1 and 1a, represents an unusual example of I (1a)-S (1) bond isomerism.
Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. A catalyst, does not appear in the overall stoichiometry of the reaction it catalyzes. you can also check out more blogs about Application In Synthesis of Tetrakis(acetonitrile)palladium(II) tetrafluoroborate!, Application In Synthesis of Cuprous thiocyanate
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”