The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Ruthenium(III) chloride xhydrate(SMILESS: Cl[Ru](Cl)Cl.[H]O[H],cas:14898-67-0) is researched.Recommanded Product: 20859-23-8. The article 《Bagasse-derived carbon-supported ruthenium nanoparticles as catalyst for efficient dehydrogenation of ammonia borane》 in relation to this compound, is published in ChemNanoMat. Let’s take a look at the latest research on this compound (cas:14898-67-0).
Recently, metal nanoparticles (NPs) have been investigated widely as heterogeneous catalysts in the hydrolysis of ammonia borane (AB). However, the method is severely challenged by the dispersion and particle size of metal NPs, and needs efficient carbon materials as supports. Herein, we describe a facile two-step synthesis strategy that takes advantage of hydrothermal synthesis and solid-phase carbonization to fabricate N-doped bagasse-derived carbon materials (BC-hs). The Ru particles can disperse well on the BC-hs carbon matrix to form Ru/BC-hs catalyst. It is found that the Ru/BC-hs catalyst, under optimized conditions (3.5 wt% Ru loading), shows a high performance for the catalytic dehydrogenation of AB, with a TOF of 354 mol H2 (molRu min)-1. The high catalytic performance of Ru/BC-hs may be ascribed to the large surface area of BC-hs (2250 m2/g) with abundant surface nitrogen and oxygen species, and more catalytically active Ru atoms are provided with the fine-grained and uniformly distributed Ru NPs. This study exhibits a universal method to design and prepare high-performance dehydrogenation catalysts, in which metal NPs are supported on biomass-derived carbon from a highly recyclable and available plant.
Different reactions of this compound(Ruthenium(III) chloride xhydrate)Application In Synthesis of Ruthenium(III) chloride xhydrate require different conditions, so the reaction conditions are very important.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”