Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 676525-77-2, is researched, SMILESS is [F-][P+5]([F-])([F-])([F-])([F-])[F-].CC(C)(C1=CC=[N]([Ir+3]23([C-]4=CC=CC=C4C5=CC=CC=[N]25)([C-]6=CC=CC=C6C7=CC=CC=[N]37)[N]8=CC=C(C(C)(C)C)C=C98)C9=C1)C, Molecular C40H40F6IrN4PJournal, Article, Research Support, Non-U.S. Gov’t, Organic Letters called Photocatalytic and Chemoselective Transfer Hydrogenation of Diarylimines in Batch and Continuous Flow, Author is van As, Dean J.; Connell, Timothy U.; Brzozowski, Martin; Scully, Andrew D.; Polyzos, Anastasios, the main research direction is diarylalkylamine preparation; diarylimine transfer hydrogenation iridium photocatalyst continuous flow.Related Products of 676525-77-2.
A visible-light photocalytic method for the chemoselective transfer hydrogenation of imines in batch and continuous flow is described. The reaction utilizes Et3N as both hydrogen source and single electron donor, enabling the selective reduction of imines derived from diarylketimines containing other reducible functional groups including nitriles, halides, esters, and ketones. The dual role of Et3N was confirmed by fluorescence quenching measurements, transient absorption spectroscopy and deuterium labeling studies. Continuous flow processing facilitates straightforward scale-up of the reaction.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”