Electric Literature of 1111-67-7, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a article£¬once mentioned of 1111-67-7
Stepwise addition of CuNCS onto [Et4N][Tp*WS3]: Design, syntheses, structures and third-order nonlinear optical properties
Stepwise reactions of [Et4N][Tp*WS3] (1) (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate) with 1-4 equiv. of CuNCS (and Et4NBr in the case of three equiv. of CuNCS) afforded the [1 + 1] to [1 + 4] addition products [Et4N][Tp*WS(mu-S) 2(CuNCS)]¡¤0.5CH2Cl2 (2¡¤0.5CH 2Cl2), [Et4N][Tp*W(mu3-S) (mu-S)2(CuNCS)2]¡¤ClCH2CH 2Cl (3¡¤ClCH2CH2Cl), [Et 4N]2[Tp*W(mu3-S)3(CuNCS) 3(mu3-Br)]¡¤1.5aniline (4¡¤1.5aniline), and {[Et4N][Tp*W(mu3-S)3(Cu-mu-SCN) 3(Cu-mu3-NCS)]}n (5). Compounds 2-5 were characterized by elemental analysis, IR spectra, UV-vis spectra, 1H NMR, and single-crystal X-ray crystallography. The cluster anion of 2 contains a [WS2Cu] core formed by addition of one CuNCS group onto the [Tp*WS3] species. The cluster anion of 3 has a butterfly-shaped [WS3Cu2] core constructed by addition of two CuNCS groups onto the [Tp*WS3] species. The cluster dianion of 4 consists of a cubane-like [Tp*WS3Cu3(mu3-Br)] core assembled by addition of three CuNCS groups onto the [Tp*WS 3] species followed by filling a mu3-Br into the void of the incomplete cubane-like [Tp*WS3(CuNCS)3] fragment. 5 has a 2D cluster-supported layer network in which each [Tp*WS3Cu3] core acting as a pyramidal 3-connecting node interconnects with the [Cu(NCS)4] units through thiocyanate bridges. In addition, the third-order nonlinear optical (NLO) performances of 2-5 in DMF were also investigated by Z-scan techniques.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1111-67-7
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”