Calancea, Sergiu et al. published their research in Inorganica Chimica Acta in 2016 | CAS: 14781-45-4

copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. Copper has continued to be one of the most utilized and important transition metal catalysts in synthetic organic chemistry. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Name: copper(ii)hexafluor-2,4-pentanedionate

A new family of multinuclear mixed-ligand copper(II) clusters: Crystal structures, magnetic properties and catecholase-like activity was written by Calancea, Sergiu;Reis, Samira G.;Guedes, Guilherme P.;Cassaro, Rafael A. Allao;Semaan, Felipe;Lopez-Ortiz, Fernando;Vaz, Maria G. F.. And the article was included in Inorganica Chimica Acta in 2016.Name: copper(ii)hexafluor-2,4-pentanedionate This article mentions the following:

The authors report a family of mixed-ligand Cu(II) clusters obtained with different nuclearities: (Et3NH)[Cu3(μ3-OH)(μ-dppi)3(μ-hfac)3] (1), [Cu4(μ-dppi)4(Hdppi)2(hfac)4] (2), [Cu5(μ-O)2(μ-dppi)(μ-Hdppi)2(μ-hfac)3(hfac)2] (3) and [Cu6(μ-O)2(μ-dppi)2(μ-Hdppi)(μ-hfac)6] (4), where hfac = hexafluoroacetylacetonate, dppi = diphenylphosphinate and Hdppi = diphenylphosphinic acid. Complexes 3 and 4 are the first examples of Cu(II) clusters containing a μ-oxo O atom and hfac as bridging ligands. The magnetic properties of all compounds showed predominant antiferromagnetic interactions and the magnetic coupling constants were evaluated using an isotropic exchange model based on the spin topol. A spin frustration phenomena was observed for the equilateral cyclic trinuclear complex (1), thus an antisym. exchange term was also considered to fit the exptl. magnetic data. The obtained J values are at -89 cm-1 to 1.7 cm-1 and were interpreted based on structural features. The electrochem. properties and catalytic activity of complexes 1 and 2 were studied and compared with the [Cu(hfac)2] precursor. Catecholase-like activity of Cu(II) complexes via oxidation of 3,5-di-tert-butylcatechol (3,5-DTBC) to 3,5-di-tert-butylquinone (3,5-DTBQ) was performed. In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4Name: copper(ii)hexafluor-2,4-pentanedionate).

copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. Copper has continued to be one of the most utilized and important transition metal catalysts in synthetic organic chemistry. It is clear from the impact copper catalysis has had on organic synthesis that copper should be considered a first line catalyst for many organic reactions.Name: copper(ii)hexafluor-2,4-pentanedionate

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”