The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, and theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. 1317-39-1, Name is Copper(I) oxide, belongs to copper-catalyst compound, is a common compound. Synthetic Route of 1317-39-1In an article, once mentioned the new application about 1317-39-1.
The impact of surface treatment of the support on the oxidation of CO over carbon-supported Wacker-type catalyts was studied. This study focused on the effect of the chemical properties of activated carbon on CO oxidation over supported PdCl2-CuCl2 and PdCl2-CuCl2-Cu(NO)32 catalyts. The surface of active carbon used to prepare supported Wacker-type catalysts was enriched with carboxylic acid and carbonyl groups by pretreating with HNO3 or adding Cu(NO3)2 as a supplementary copper precursor. These surface groups improved the hydrophilicity and facilitated the formation of an active copper phase (Cu2Cl(OH)3). The effects were stronger, particularly on the formation of Cu2Cl(OH)3, when Cu(NO3)2 was combined with CuCl2 as catalyst precursors. The acceleration of CO oxidation can be attributed to the formation of the active copper phase and the improved hydrophilicity.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Synthetic Route of 1317-39-1, you can also check out more blogs aboutSynthetic Route of 1317-39-1
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”