The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 16606-55-6, Name is (R)-4-Methyl-1,3-dioxolan-2-one, SMILES is O=C1OC[C@@H](C)O1, in an article , author is Bhargava Reddy, Mandapati, once mentioned of 16606-55-6, Recommanded Product: 16606-55-6.
Visible-light induced copper(i)-catalyzed oxidative cyclization of o-aminobenzamides with methanol and ethanol via HAT
The use of the in situ generated ligand-copper superoxo complex absorbing light energy to activate the alpha C(sp(3))-H of MeOH and EtOH via the hydrogen atom transfer (HAT) process for the synthesis of quinazolinones by oxidative cyclization of alcohols with o-aminobenzamide has been investigated. The synthetic utility of this protocol offers an efficient synthesis of a quinazolinone intermediate for erlotinb (anti-cancer agent) and 30 examples were reported.
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Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”