Let¡¯s face it, organic chemistry can seem difficult to learn. HPLC of Formula: CCuNS. Especially from a beginner¡¯s point of view. Like HPLC of Formula: CCuNS, Name is Cuprous thiocyanate. In a document type is Article, introducing its new discovery.
Extended supramolecular structures derived from metal pseudohalides and 4,4?-bipyridinium derivative: Synthesis, structures and optical properties
Four novel extended supramolecular structures based on pseudohalides (SCN) and the flexible cationic ligand 1,4-bis(4,4?-bipyridinium)butane ditetrafluoroborate (bbpyb), namely [bbpyb][Hg(SCN)4] (1), [Cu2(bbpyb)(SCN)4]n (2), [Ag2(bbpyb)(SCN)4]n (3) and [Cu6(bbpyb)(SCN)8]n (4) have been solvothermally synthesized and characterized by IR spectroscopy, thermal gravimetric analysis(TGA), PXRD, UV-Vis diffuse reflectance spectra and single-crystal X-ray diffraction in the solid state. Compound 1 is a 0D supramolecular structure consisted of one linear cationic ligand bbpyb2+ and inorganic mononuclear anion [Hg(SCN)4]2-. Compounds 2 and 3 exhibit infinite two-dimensional anionic architecture, which represent the same (6,3) topology. In compound 4, the cationic ligand bbpyb2+ bridge [Cu6(SCN)8] cluster unit to generate a 3D coordination framework. The structural diversities show that the pseudohalides (SCN) and cationic ligand should very likely be excellent candidates to construct higher dimensional extend supramolecular architectures. In addition, the optical band gap and photocatalytic properties of compounds 1-4 were also investigated.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”