Recommanded Product: [Ir(dtbbpy)(ppy)2]PF6. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Synthesis of oxindoles via visible light photoredox catalysis. Author is Ju, Xuhui; Liang, Yan; Jia, Pingjing; Li, Weifei; Yu, Wei.
2-Electron-withdrawing-group-substituted 2-bromoanilides can be converted to the corresponding 3,3-disubstituted oxindoles with high efficiency under visible light irradiation by using fac-Ir(ppy)3 as the photoredox catalyst. This protocol is suitable for the synthesis of oxindoles with chloro and bromo atoms attached to the Ph ring.
Compound(676525-77-2)Recommanded Product: [Ir(dtbbpy)(ppy)2]PF6 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound([Ir(dtbbpy)(ppy)2]PF6), if you are interested, you can check out my other related articles.
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”