Continuously updated synthesis method about Copper(I) bromide

With the complex challenges of chemical substances, we look forward to future research findings about Copper(I) bromide

Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 7787-70-4, name is Copper(I) bromide. This compound has unique chemical properties. The synthetic route is as follows. 7787-70-4

A mixture of PLN(37.6 mg, 0.2 mmol) containing CH3ONa (11.8 mg, 0.22 mmol) andCuBr (22 mg, 0.2 mmol) in methanolic solution (10 mL) was refluxed for 2 h, followed by addition of 1,10-phenanthroline (36 mg,0.2 mmol) in methanol (10 mL). The mixture was stirred for another 30 min at room temperature to give a dark-red solution and then filtered.The filtrate was kept in air for a week, forming dark-red block crystals. The crystals were isolated, washed three times with distilled water and dried in a vacuum desiccator containing anhydrous CaCl2. Yield: 87.9 mg (81%). Anal. Calcd for C24H19BrCuN2O4 (542.86): C,53.10; H, 3.52 and N, 5.16. Found: C, 53.12; H, 3.53 and N, 5.17. IR(KBr, cm-1): 3500, 3041, 1986, 1837, 1628, 1590, 1568, 1510, 1418,1344, 1196, 1159, 1106, 993, 855, 773, 720, 672, 631, 551, 548, 528,468, 455, 430.

With the complex challenges of chemical substances, we look forward to future research findings about Copper(I) bromide

Reference£º
Article; Gou, Yi; Zhang, Zhan; Qi, Jinxu; Liang, Shichu; Zhou, Zuping; Yang, Feng; Liang, Hong; Journal of Inorganic Biochemistry; vol. 153; (2015); p. 13 – 22;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”